potash

Potash and Phosphate help feed the world

More than 90 percent of phosphate and potash production is used to fertilize soil, increasing America’s crop yields in a sustainable manner. The United States produced $3.6 billion worth of phosphate and potash in 2013, supporting nearly 4,000 direct, indirect and induced jobs. Altogether, industries utilized all minerals to add more than $2.4 trillion to the U.S. GDP in 2013.

Below is an infographic from the National Mining Association which gives the basics for potash and phosphate.

I notice that the map in the infographic shows no production from Arizona. That may soon change. Recent discovery of potash in the Holbrook Basin has inferred reserves of 66 million metric tons of contained potash (K2O). See my post here.

 NMA_Potash_Potassium_Infographic_11-20-final

The value of mining in Arizona

Without minerals, we would not have electricity, food, or shelter. Minerals make today’s technology-based life possible, but that’s something many of us take for granted. We want the benefits from those minerals, but some want mining of minerals to be in somebody else’s neighborhood.  The importance of mining has long been recognized:

If we remove metals from the service of man, all methods of protecting and sustaining health and more carefully preserving the course of life are done away with.  If there were no metals, men would pass a horrible and wretched existence in the midst of wild beasts…  -Georgius Agricola, in De Re Metallica, 1556.

For Arizona, it is not just metals.  Arizona produces sand and gravel, limestone for cement production, coal for electrical generation, and a variety of industrial minerals which contribute almost $2 billion to Arizona’s economy (see here).

Arizona has a long history of mining.  There is archeological evidence that cinnabar, coal, turquoise, clay, pigments, and other minerals were mined in Arizona beginning at least 3,000 years ago. (See A History of Mining in AZ by the Arizona Mining Association.)

According to the Arizona Mining Association, Arizona currently produces 68% of domestically mined copper.  With that copper production comes by-product molybdenum, gold, silver, platinum, and rhenium.  Incidentally, The Sierrita Mine south of Tucson is currently the onlydomestic producerof rhenium, a metal used in high-temperature, super-alloy turbine blades for jet aircraft and other land-based turbines.  The Sierrita plant processes output from other mines on a toll basis. It may soon be joined by a second rhenium plant at the Kennecott (Rio Tinto) mine in Utah.

The direct and indirect economic impact of copper mining on Arizona’s economy is about $4.6 billion annually.  That includes $3.2 billion in personal income,  $500 million in state and local government revenues, and 49,800 high-paying jobs for Arizonans. Average labor income of mining company employees (including benefits) is $108,000 per worker vs. $47,000 for all Arizona workers.  If we add in non-metallic, non-fuel, minerals, then Arizona produced about $8 billion worth of mineral products in 2012 according to the U.S. Geological Survey.  Arizona ranks second, after Nevada, in value of total mineral production.  The U.S. total value of mineral production was about $76 billion which supported more than 1.2 million jobs in 2012.

Arizona is endowed with great mineral resources as shown on the map below prepared by the Arizona Geological Survey.

mineralmap

Currently ASARCO and Freeport-McMoRan Copper & Gold are the two biggest copper producers in the state.  ASARCO operates three mines and a smelter. According to the Southern Arizona Business Coalition, in 2012 ASARCO paid wages and benefits of $215.8 million, property, severance, and sales taxes of $47.2 million, and employed 2,198 people in Arizona. Freeport operates mines in Safford, Morenci, Bagdad, Miami, and Sierrita.  They paid wages and operational spending of $860 million in 2012, taxes of $274 million while employing 7,600 people directly and indirectly employing an additional 30,000 people.

In addition to past and current mining, there are many projects on the horizon, some in the exploratory stage, others navigating the byzantine regulatory permitting process.  (See my posts: Mining and the bureaucracy and How NEPA crushes productivity)

Perhaps the largest project is that of Resolution Copper near the town of Superior just west of the famed Globe-Miami mining district and just north of ASARCO’s Ray mine.  This is a bold undertaking because the orebody is 7,000 feet below the surface.  Resolution says that at peak production, this mine will be the largest copper mine in North America, producing over one billion pounds of copper per year.  Resolution estimates that over the 64-year life of the mine, the project will generate $61.4 billion in economic value, provide $20 billion in tax revenues, and provide 3,700 permanent jobs.

The Rosemont copper mine south of Tucson is nearing the end of its long journey through the regulatory maze, and mine construction may begin early next year.  This mine will generate 2,900 Arizona jobs and inject $19 billion into Arizona’s economy and pay $404 million in local taxes over its 20-year projected life.  The mine expects to produce 243 million pounds of copper per year.

Curis Resources is developing an in-situ copper mine near Florence, Arizona.  In this project, instead of mining rock, Curis Resources “seeks to dissolve copper minerals from an underground deposit by introducing water with a lowered-pH (making it slightly acidic).This low-PH, water-based solution dissolves the copper and allows it to be pumped to the surface through a continuous loop water treatment system.”  This deposit, lying 400-to 1200 feet below the surface contains approximately 2.84 billion pounds of copper.

Curis estimates that over the projected 28-year life of the project, it will generate $2.2 billion in economic activity for the state of Arizona, $1.1 billion in economic activity for Pinal County, $325 million in taxes and royalties for Arizona government, and $1.46 billion in increased personal income in Arizona, 170 direct jobs at the project site in Florence, and 681 jobs in the state of Arizona.

TheI-10 copper deposit, located along Interstate 10 between Benson and Willcox, Arizona, is being investigated as another in-situ copper leaching project by  Excelsior Mining Corporation, a Canadian junior company. They estimate the deposit currently contains an indicated oxide copper resource of 3.21 billion pounds and an additional inferred oxide copper resource of 0.88 billion pounds.

Wildcat Silver Corporation is in the exploration stage of its Hermosa Project which is evaluating the silver-manganese potential in the historic Hardshell mining district near Patagonia in Southern Arizona. Their preliminary economic assessment estimates a measured and indicated resource of 236 million ounces of silver and an inferred silver resource of an additional 79 million ounces.  Project life is estimated at 16 years.  Wildcat estimates that annual production will be 4.1 million ounces of silver, 233,000 tons of manganese carbonate, 20,187 tons of zinc cathode, and 960 tons of copper.

Copper Creek is an old mining district located on the east bank of the San Pedro River and on the western slope of the Galiuro Mountains about 75 miles northeast of Tucson. The property has been acquired by Redhawk Resources, a Canadian junior mining company that plans to develop an underground mine for copper, molybdenum, and silver.  Redhawk estimates a resource of 7.75 billion pounds of copper, 150 million pounds of molybdenum, and 32 million ounces of silver.

The Oracle Ridge mine is a small, underground copper mine in the Santa Catalina Mountains just north of Tucson. The mine was operated intermittently, most recently from 1991-1996. The mine is being developed by a junior Canadian mining company, Oracle Ridge Copper (project website).  The company anticipates employing about 200 people to run the mine which has a projected life of 11 years. The mine will produce 140 tons of concentrate (about 30% copper) a day which will be trucked off the mountain and transported to a smelter.

In northern Arizona, near the Grand Canyon are over 1,300 known or suspected breccia pipes many of which contain uranium oxide as well as sulfides of copper, zinc, silver, and other metals. According to the Arizona Geological Survey, “Total breccia-pipe uranium production as of Dec. 31, 2010, has been more than 10,700 metric tons (23.5 million pounds) from nine underground mines, eight of which are north of Grand Canyon near Kanab Creek.”  This area is mired in fears of contamination of the Colorado River (see Uranium mining and its potential impact on Colorado River water) and a 20-year, million-acre mineral entry withdrawal by the Department of the Interior.

In northeastern Arizona there is potential for a major potash deposit. American West Potash has recently delineated, a considerable resource estimated at  158 million metric tons of sylvinite (a mixture of sodium and potassium chloride, not to be confused with sylvanite, a gold telluride), with about 16 million metric tonnes of K2O; and inferred resources of 560 million metric tonnes of sylvinite with just over 66 million metric tons of K2O in the Holbrook Basin, about 30 miles east of Holbrook, Arizona.

The Holbrook Basin area also holds potential for helium and shale oil resources.

Arizona currently has three producing gold mines and several other prospects being actively explored for gold (see here).

“In 2011, the state of Arizona led the United States in the production of gemstones. Arizona has long been famous as a producer of turquoise, peridot and petrified wood. Gemstones such as azurite, chrysocolla and malachite are associated with the Arizona’s many copper deposits and have a long history of being produced there. Agate, amethyst, garnet, jade, jasper, obsidian, onyx, and opal have all been found in Arizona and used to make gems.” – Geology.com

As you can see, besides currently producing mines, Arizona holds future potential that will add jobs and economic value to the local, state, and national economy – if they can get through the bureaucratic regulatory maze.

Remember, the value of mining is not just the money, it is in providing the products we need to keep our civilization going.  If it can’t be grown, it has to be mined.

Arizona may become a major producer of potash

What is potash?  No, it’s not residue from a joint. It’s a potassium salt used for fertilizer and in chemical processing.  A newly delineated deposit in the Holbrook Basin, about 30 miles east of Holbrook, holds a considerable resource estimated at  158 million metric tonnes of sylvinite, with about 16 million metric tonnes of K2O; and Inferred Resources of 560 million metric tonnes of sylvinite with just over 66 million metric tons of K2O.  Sylvinite is a mixture of potassium chloride and sodium chloride (not to be confused with sylvanite, a gold telluride mineral).

potash-location

The deposit is hosted in evaporite deposits within Pennsylvanian to Permian aged siliciclastic sediments.  Potash occurs as discreet mineralized horizons within the uppermost halite beds of this evaporite sequence.  See section below.  Evaporite minerals are produced from the evaporation of mineral-laden water in an enclosed basin.  Just think of what would be left if the Great Salt Lake in Utah evaporated.  Similar events have occurred many times.  In fact, much of Phoenix is underlain by evaporite deposits.

potash-section

A 100-page technical report prepared by North Rim Exploration for the property owner, American West Potash, is available here.

For some background on potash, the following is from the USGS mineral commodity summary for 2011:

Domestic Production and Use

In 2010, the production value of marketable potash, f.o.b. mine, was about $540 million. Potash was produced in Michigan, New Mexico, and Utah. Most of the production was from southeastern New Mexico, where two companies operated three mines. New Mexico sylvinite and langbeinite ores were beneficiated by flotation, dissolution-recrystallization, heavy-media separations, or combinations of these processes, and provided more than 75% of total U.S. producer sales. In Utah, which has three operations, one company extracted underground sylvinite ore by deep-well solution mining. Solar evaporation crystallized the sylvinite ore from the brine solution, and a flotation process separated the potassium chloride (muriate of potash or MOP) from byproduct sodium chloride. Two companies processed surface and subsurface brines by solar evaporation and flotation to produce MOP, potassium sulfate (sulfate of potash or SOP), and byproducts. In Michigan, one company used deep-well solution mining and mechanical evaporation for crystallization of MOP and byproduct sodium chloride.

The fertilizer industry used about 85% of U.S. potash sales, and the chemical industry used the remainder. More than 60% of the produced potash was MOP. Potassium magnesium sulfate (sulfate of potash-magnesia or SOPM) and SOP, which are required by certain crops and soils, also were produced.

World Resources

Estimated domestic potash resources total about 7 billion tons. Most of these lie at depths between 1,800 and 3,100 meters in a 3,110-square-kilometer area of Montana and North Dakota as an extension of the Williston Basin deposits in Saskatchewan, Canada. The Paradox Basin in Utah contains resources of about 2 billion tons, mostly at depths of more than 1,200 meters. The Holbrook Basin of Arizona contains resources of about 1 billion tons. A large potash resource lies about 2,100 meters under central Michigan. The U.S. reserves figure above includes approximately 40 million tons in central Michigan. Estimated world resources total about 250 billion tons.

Substitutes

There are no substitutes for potassium as an essential plant nutrient and an essential nutritional requirement for animals and humans. Manure and glauconite (greensand) are low-potassium-content sources that can be profitably transported only short distances to the crop fields.

See also:

Arizona Geologic History: Chapter 1, Precambrian Time When Arizona was at the South Pole

Arizona Geological History: Chapter 2, Cambrian and Ordovician Time

Arizona Geological History: Chapter 3: Devonian to Permian Time

Arizona Geological History Chapter 4: Triassic Period

Arizona Geological History Chapter 5: Jurassic Time

Arizona Geological History 6, The Cretaceous Period

Arizona Geological History 7: The Cenozoic Era

Arizona Geology: earthquakes, potash and education

The Arizona Geological Survey has just released its newest issue of Arizona Geology Magazine. This issue features photos of earth fissures in Cochise County and an update on seismicity in Arizona. Seismometers recorded 17 earthquakes in Arizona from January to March.

Also featured is “SCINEWS” a link between classroom content and everyday life through the use of science current events. This adds relevancy to science education.

The new issue presents a summary of oil and gas activities in Arizona. Included within that article is a report on Potash mining. What’s that? Potash is potassium salts used mainly for fertilizers. Exploration is being conducted west of Petrified Forest National Park near Holbrook. Mining is usually by in situ solution extraction rather than digging holes.

Also featured  are papers on evaluation of basins for carbon dioxide sequestration and geothermal potential.

There are also links to new, downloadable publications. One not to miss is a paper on geological hazards in Sabino Canyon. You can see the whole issue here.